Here in Europe "Euro-Super" with 95 octane ROZ (90 octane ROZ/MOZ in USA) is the lowest available, "Normal" with 91 Octane (87 in USA) was stopped some years ago.
There is "Super E5" with max. 5% bio-ethanol added and "Super E10" with up to 10% bio-fuel.
I always take the more expensive E5 (E10 is politically subventioned), for political reasons and because in the classic car scene it's said, that too much bio-ethanol can destroy the carburator and the gaskets of the fuel system.
The HEMI can bear E10, it's said, but I dont trust that.
Some people say, that with "Super plus" (98 Octane Europe, 93 Octane USA) the HEMI shall run better, but this is more a opinion or feeling.
We have also "Ultimate" (ARAL) or "V-Power" (Shell) with 100 or 102 Octane (95 and 97 in USA) -20 €-Cent per liter more, actually over 2€ per liter-, but this you only need for some high-end engines - which the HEMI clearly is not.
Sometimes, when I'm countries with cheap fuel as Luxemburg, I grant my car such stuff as a special goodie, but at least it's a rip-off by the fuel companies.
At our USA-trip in 2008 we had a Dodge Grand Caravan with the "eco fuel" 3.8 liter engine - a terrible clunker, lame, loud and it "runs like a bag of walnuts", as we say in German.
We thought, the eco-ethanol-fuel was the reason for the terrible running, so we filled only Premium 93, but it didn't get better. We creeped with max.70 MPH along the Appalachians, more was not possible, even with full throttle 🙈
So the "eco-fuel" was not the reason - the 3.8 liter was sh*t.
Indeed, the 3.6 liter "Pentastar" Grand Caravan we had four years later on our Florida-trip was noticeable better.
I must admit, that after this experience I said "Never ever MOPAR junk in my household", but well, since August 2020 I'm a totally happy and satisfied HEMI owner 🫣